POLIELEKTROLITHO, elektrolithoi polimeri, polimerhoe, kn dar mahlulho ba ionho judo (dissotsiatsiya) shuda metavonand. Polielektrolitho ba kislotahoi polimeri (masalan, kislotahoi poliakrilat), asoshoi polimeri (polivinilpiridiniy) va poliamfol i t h o (sopolimerhoe, ki dar tarkibashon ham guruhhoi asosi va ham guruhhoi kislotagi dorand) taqsim meshavand. Muhimtarin biopolimerho — safedaho va kislotahoi nukleat az jumlai Polielektrolitho meboshand. Khususiyati molekulahoi Polielektrolithoro dar mahlul tasiri elektrostatikii guruhhoi zaryadnoki silsilai polimeri bo yakdigar va bo ionhoi khurdmolekulai mahlul muayyan mekunad. Dar natijai aksuttasiri guruhhoi zaryadashon yakkhela konformatsiya va andozaya makromolekulaho dar mahlul, khususiyati fizikiyu khimiyavii mahlulho khele tagyir meyobad (masalan, galizii mahlul mumkin ast hazorho bor ziyod shavad). Binobar murakkab budani prosessi dissotsiatsiyai Polielektrolitho khosiyathoi khimiyavii Polielektrolithoro zimni nazariyai mahlulhoi muqarrari manidod kardan amri mahol ast.
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